1,10-Phenanthrolin-1-ium 2-carboxy-4,5-dichlorobenzoate

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9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate

In the title organic salt, C(18)H(14)N(3)O(+)·ClO(4) (-)·CH(4)O, there is a π-π stacking inter-action between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid-centroid distance and 3.354 Å for the perpendicular distance. There is also a relatively close contact between a C-H bond and a symmetry-related pyridine ring. There are classical N-H⋯O ...

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5,6-Dioxo-1,10-phenanthrolin-1-ium nitrate

In the title salt, C(12)H(7)N(2)O(2) (+)·NO(3) (-), the monoprotonated cation is connected to the nitrate anion by a hydrogen bond. Weak C-H⋯O hydrogen bonds hold the planar cations together in a layer structure.

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5,6-Dioxo-1,10-phenanthrolin-1-ium chloride

The title compound, C(12)H(7)N(2)O(2) (+)·Cl(-), is isostructural with its bromide analogue. The compound exhibits a layered structure in which all atoms lie on a crystallographic mirror plane. N(+)-H⋯Cl(-) hydrogen bonds, C-H⋯O and C-H⋯Cl(-) contacts are formed within each layer. The perpendicular separation between the layers is 3.141 (1) Å.

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Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate

In the crystal structure of the title compound, (C12H9N2)2[ZnCl4]·H2O, the two independent 1,10-phenanthrolinium cations are bridged by the water mol-ecule and the tetrahedral tetrachloridozincate anion via N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds, forming chains along [100]. The chains are linked via C-H⋯Cl hydrogen bonds and a number of π-π inter-actions [centroid-centroid distances vary from ...

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